Cargando…

Reversible [4 + 2] cycloaddition reaction of 1,3,2,5-diazadiborinine with ethylene

Under ambient conditions, a [4 + 2] cycloaddition reaction of 1,3,2,5-diazadiborinine 1 with ethylene afforded a bicyclo[2.2.2] derivative 2, which was structurally characterized. The cyclization process was found to be reversible, and thus retro-[4 + 2] cycloaddition reproduced 1 quantitatively, co...

Descripción completa

Detalles Bibliográficos
Autores principales:	Wu, Di, Ganguly, Rakesh, Li, Yongxin, Hoo, Sin Ni, Hirao, Hajime, Kinjo, Rei
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952552/ https://www.ncbi.nlm.nih.gov/pubmed/29861951 http://dx.doi.org/10.1039/c5sc03174e

Ejemplares similares

1,3,2,5-Diazadiborinine featuring nucleophilic and electrophilic boron centres
por: Wu, Di, et al.
Publicado: (2015)

Ambiphilic boron in 1,4,2,5-diazadiborinine
por: Wang, Baolin, et al.
Publicado: (2016)

Boron-based stepwise dioxygen activation with 1,4,2,5-diazadiborinine
por: Wang, Baolin, et al.
Publicado: (2018)

Diverse reactivity of a tricoordinate organoboron L(2)PhB: (L = oxazol-2-ylidene) towards alkali metal, group 9 metal, and coinage metal precursors
por: Kong, Lingbing, et al.
Publicado: (2015)

Crystalline boron-linked tetraaminoethylene radical cations
por: Su, Yuanting, et al.
Publicado: (2017)

Redox-induced reversible [2 + 2] cycloaddition of an etheno-fused diporphyrin
por: Miyagawa, Kazuya, et al.
Publicado: (2021)

Dearomative [3 + 2] cycloaddition reaction of nitrobenzothiophenes with nonstabilized azomethine ylides
por: Wang, Kai-Kai, et al.
Publicado: (2020)

Reversible and Irreversible [2+2] Cycloaddition Reactions of Heteroallenes to a Gallaphosphene
por: Sharma, Mahendra K., et al.
Publicado: (2021)

Mechanistic Studies of CO(2) Cycloaddition Reaction Catalyzed by Amine-Functionalized Ionic Liquids
por: Chen, Jian, et al.
Publicado: (2019)

1,2-Addition and cycloaddition reactions of niobium bis(imido) and oxo imido complexes
por: Fostvedt, Jade I., et al.
Publicado: (2020)

B−B Cleavage and Ring‐Expansion of a 1,4,2,3‐Diazadiborinine with N‐Heterocyclic Carbenes
por: Thiess, Torsten, et al.
Publicado: (2019)

Gobernantes de México, 1325-1911
Publicado: (1960)

[4 + 2] and [2 + 4] cycloaddition reactions on single- and double-stranded DNA: a dual-reactive nucleoside
por: Bujalska, Anna, et al.
Publicado: (2022)

Synthesis of distibiranes and azadistibiranes by cycloaddition reactions of distibenes with diazomethanes and azides
por: Weinert, Hanns M., et al.
Publicado: (2022)

Azide–alkyne cycloaddition reactions in water via recyclable heterogeneous Cu catalysts: reverse phase silica gel and thermoresponsive hydrogels
por: Lim, Minkyung, et al.
Publicado: (2018)

Reaction of a diaryldigermyne with ethylene
por: Sasamori, Takahiro, et al.
Publicado: (2015)

Synthesis of 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions of azobenzenes with phosphaalkynes
por: Liang, Wenbin, et al.
Publicado: (2020)

Understanding the different reactivity of (Z)- and (E)-β-nitrostyrenes in [3+2] cycloaddition reactions. An MEDT study
por: Ríos-Gutiérrez, Mar, et al.
Publicado: (2021)

Asymmetric 1,3-dipolar cycloaddition reaction of chiral 1-alkyl-1,2-diphospholes with diphenyldiazomethane
por: Ganushevich, Yulia, et al.
Publicado: (2020)

Transition metal catalyzed [6 + 2] cycloadditions
por: Anand, Amit, et al.
Publicado: (2019)

A visible-light activated [2 + 2] cycloaddition reaction enables pinpointing carbon–carbon double bonds in lipids
por: Feng, Guifang, et al.
Publicado: (2020)

Cascade synthesis of 2,4-disulfonylpyrroles by the sulfonylation/[2 + 3]-cycloaddition reactions of gem-dibromoalkenes with arylsulfonyl methyl isocyanides
por: Salehi, Parvin, et al.
Publicado: (2021)

Accessing unusual heterocycles: ring expansion of benzoborirenes by formal cycloaddition reactions
por: Sindlinger, Marvin, et al.
Publicado: (2023)

Pericyclases for cycloaddition
por: Zhang, Bo, et al.
Publicado: (2022)

La Ciudad de México, 1325-1982 /
por: Benítez, Fernando, 1912-2000
Publicado: (1981)

Reversibility and reactivity in an acid catalyzed cyclocondensation to give furanochromanes – a reaction at the ‘oxonium-Prins’ vs. ‘ortho-quinone methide cycloaddition’ mechanistic nexus
por: Nielsen, Christian D.-T., et al.
Publicado: (2018)

Isolation of a Cyclic (Alkyl)(amino)germylene
por: Wang, Liliang, et al.
Publicado: (2016)

Novel porous organocatalysts for cycloaddition of CO(2) and epoxides
por: Kolle, Joel M., et al.
Publicado: (2019)

BODIPY as electron withdrawing group for the activation of double bonds in asymmetric cycloaddition reactions
por: Guerrero-Corella, Andrea, et al.
Publicado: (2019)

Rejuvenation of dearomative cycloaddition reactions via visible light energy transfer catalysis
por: Palai, Angshuman, et al.
Publicado: (2023)

Aromatic nature of neutral and dianionic 1,4-diaza-2,3,5,6-tetraborinine derivatives
por: Ota, Kei, et al.
Publicado: (2021)

México-Tenochtitlán, 1325-1975 : pasado, presente y futuro de una gran ciudad
Publicado: (1976)

Intramolecular photochemical [2 + 1]-cycloadditions of nucleophilic siloxy carbenes
por: Bunyamin, Amanda, et al.
Publicado: (2022)

Effect of substituents and promoters on the Diels–Alder cycloaddition reaction in the biorenewable synthesis of trimellitic acid
por: Khan, Tuhin Suvra, et al.
Publicado: (2020)

Stereoselective synthesis of [2.2]triphenylenophanes via intramolecular double [2 + 2 + 2] cycloadditions
por: Kawai, Yuya, et al.
Publicado: (2023)

Potassium iodide–polyethylene glycol catalyzed cycloaddition reaction of epoxidized soybean oil fatty acid methyl esters with CO(2)
por: Liu, Wei, et al.
Publicado: (2018)

Robust acid–base Ln-MOFs: searching for efficient catalysts in cycloaddition of CO(2) with epoxides and cascade deacetalization–Knoevenagel reactions
por: Si, Xuezhen, et al.
Publicado: (2022)

Palladium-catalysed enantio- and regioselective (3 + 2) cycloaddition reactions of sulfamidate imine-derived 1-azadienes towards spirocyclic cyclopentanes
por: Pham, Quoc Hoang, et al.
Publicado: (2023)

[3 + 2]-Cycloaddition reaction of sydnones with alkynes
por: Hladíková, Veronika, et al.
Publicado: (2018)

Sustainable Construction of Heterocyclic 1,2,3-Triazoles by Strict Click [3+2] Cycloaddition Reactions Between Azides and Alkynes on Copper/Carbon in Water
por: Aflak, Noura, et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_bu8r8ig9tng40c9sgs7iubr0du