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Supramolecular aggregates of single-molecule magnets: exchange-biased quantum tunneling of magnetization in a rectangular [Mn(3)](4) tetramer
The syntheses and properties of four magnetically-supramolecular oligomers of triangular Mn(3) units are reported: dimeric [Mn(6)O(2)(O(2)CMe)(8)(CH(3)OH)(2)(pdpd)(2)] (3) and [Mn(6)O(2)(O(2)CMe)(8)(py)(2)(pdpd)(2)](ClO(4))(2) (4), and tetrameric [Mn(12)O(4)(O(2)CR)(12)(pdpd)(6)](ClO(4))(4) (R = Me...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952871/ https://www.ncbi.nlm.nih.gov/pubmed/29896376 http://dx.doi.org/10.1039/c5sc02599k |