Supramolecular aggregates of single-molecule magnets: exchange-biased quantum tunneling of magnetization in a rectangular [Mn(3)](4) tetramer

The syntheses and properties of four magnetically-supramolecular oligomers of triangular Mn(3) units are reported: dimeric [Mn(6)O(2)(O(2)CMe)(8)(CH(3)OH)(2)(pdpd)(2)] (3) and [Mn(6)O(2)(O(2)CMe)(8)(py)(2)(pdpd)(2)](ClO(4))(2) (4), and tetrameric [Mn(12)O(4)(O(2)CR)(12)(pdpd)(6)](ClO(4))(4) (R = Me...

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Detalles Bibliográficos
Autores principales: Nguyen, Tu N., Wernsdorfer, Wolfgang, Shiddiq, Muhandis, Abboud, Khalil A., Hill, Stephen, Christou, George
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952871/
https://www.ncbi.nlm.nih.gov/pubmed/29896376
http://dx.doi.org/10.1039/c5sc02599k

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