Bond-bending isomerism of Au(2)I(3)(–): competition between covalent bonding and aurophilicity

We report a joint photoelectron spectroscopy and theoretical investigation of the gaseous Au(2)I(3)(–) cluster, which is found to exhibit two types of isomers due to competition between Au–I covalent bonding and Au–Au aurophilic interactions. The covalent bonding favors a bent IAuIAuI(–) structure w...

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Detalles Bibliográficos
Autores principales: Li, Wan-Lu, Liu, Hong-Tao, Jian, Tian, Lopez, Gary V., Piazza, Zachary A., Huang, Dao-Ling, Chen, Teng-Teng, Su, Jing, Yang, Ping, Chen, Xin, Wang, Lai-Sheng, Li, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952886/
https://www.ncbi.nlm.nih.gov/pubmed/29896343
http://dx.doi.org/10.1039/c5sc03568f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952886/
https://www.ncbi.nlm.nih.gov/pubmed/29896343
http://dx.doi.org/10.1039/c5sc03568f

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