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Bond-bending isomerism of Au(2)I(3)(–): competition between covalent bonding and aurophilicity
We report a joint photoelectron spectroscopy and theoretical investigation of the gaseous Au(2)I(3)(–) cluster, which is found to exhibit two types of isomers due to competition between Au–I covalent bonding and Au–Au aurophilic interactions. The covalent bonding favors a bent IAuIAuI(–) structure w...
| Autores principales: | , , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952886/ https://www.ncbi.nlm.nih.gov/pubmed/29896343 http://dx.doi.org/10.1039/c5sc03568f |