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Gold(iii) tetraarylporphyrin amino acid derivatives: ligand or metal centred redox chemistry?

Meso tetraarylporphyrinato gold(iii) cations bearing different substituents at the aryl substituents (COOMe, COOH, NO(2), NH(2), NHAc, H, O(n)Bu, CF(3)) were prepared and characterised. Their reversible one-electron reductions were studied by (spectro)electrochemical means as well as by selective ch...

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Detalles Bibliográficos
Autores principales: Preiß, Sebastian, Melomedov, Jascha, Wünsche von Leupoldt, Anica, Heinze, Katja
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952892/
https://www.ncbi.nlm.nih.gov/pubmed/29896349
http://dx.doi.org/10.1039/c5sc03429a