Magnesium-catalysed nitrile hydroboration

A β-diketiminato n-butylmagnesium complex is presented as a selective precatalyst for the reductive hydroboration of organic nitriles with pinacolborane (HBpin). Stoichiometric reactivity studies indicate that catalytic turnover ensues through the generation of magnesium aldimido, aldimidoborate and...

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Detalles Bibliográficos
Autores principales: Weetman, Catherine, Anker, Mathew D., Arrowsmith, Merle, Hill, Michael S., Kociok-Köhn, Gabriele, Liptrot, David J., Mahon, Mary F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952893/
https://www.ncbi.nlm.nih.gov/pubmed/29896350
http://dx.doi.org/10.1039/c5sc03114a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952893/
https://www.ncbi.nlm.nih.gov/pubmed/29896350
http://dx.doi.org/10.1039/c5sc03114a

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