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Magnesium-catalysed nitrile hydroboration
A β-diketiminato n-butylmagnesium complex is presented as a selective precatalyst for the reductive hydroboration of organic nitriles with pinacolborane (HBpin). Stoichiometric reactivity studies indicate that catalytic turnover ensues through the generation of magnesium aldimido, aldimidoborate and...
Autores principales: | Weetman, Catherine, Anker, Mathew D., Arrowsmith, Merle, Hill, Michael S., Kociok-Köhn, Gabriele, Liptrot, David J., Mahon, Mary F. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952893/ https://www.ncbi.nlm.nih.gov/pubmed/29896350 http://dx.doi.org/10.1039/c5sc03114a |
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