Ligand-controlled insertion regioselectivity accelerates copolymerisation of ethylene with methyl acrylate by cationic bisphosphine monoxide–palladium catalysts

A new series of palladium catalysts ligated by a chelating bisphosphine monoxide bearing diarylphosphino groups (aryl-BPMO) exhibits markedly higher reactivity for ethylene/methyl acrylate copolymerisation when compared to the first generation of alkyl-BPMO–palladium catalysts that contain a dialkyl...

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Detalles Bibliográficos
Autores principales: Mitsushige, Yusuke, Carrow, Brad P., Ito, Shingo, Nozaki, Kyoko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952993/
https://www.ncbi.nlm.nih.gov/pubmed/29896357
http://dx.doi.org/10.1039/c5sc03361f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5952993/
https://www.ncbi.nlm.nih.gov/pubmed/29896357
http://dx.doi.org/10.1039/c5sc03361f

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