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Zwitterionic and biradicaloid heteroatomic cyclopentane derivatives containing different group 15 elements

The formal cyclopentane-1,3-diyl derivatives [E(1)(μ-NTer)(2)({E(2)C} = NDmp)] (Ter = 2,6-dimesityl-phenyl, Dmp = 2,6-dimethylphenyl) were prepared by 1,1-insertion of CNDmp into the N–E(2) bond of [E(1)(μ-NTer)(2)E(2)] (E(1) = N, P; E(2) = P, As). The insertion does not occur for E(1) = E(2) = As o...

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Detalles Bibliográficos
Autores principales: Hinz, Alexander, Schulz, Axel, Villinger, Alexander
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5953028/
https://www.ncbi.nlm.nih.gov/pubmed/29896358
http://dx.doi.org/10.1039/c5sc03515e