The ligand unwrapping/rewrapping pathway that exchanges metals in S-acetylated, hexacoordinate N(2)S(2)O(2) complexes

The effect of S-acetylation in MN(2)S(2) complexes on metal exchange reactivity was examined in a series of MN(2)S(2)O(2) complexes. While clean exchange processes do not occur for the MN(2)S(2) derivatives where formation of S-bridged aggregates predominate, acetylation permits the metal exchange w...

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Detalles Bibliográficos
Autores principales: Denny, J. A., Foley, W. S., Todd, A. D., Darensbourg, M. Y.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5954489/
https://www.ncbi.nlm.nih.gov/pubmed/29896341
http://dx.doi.org/10.1039/c5sc02269j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5954489/
https://www.ncbi.nlm.nih.gov/pubmed/29896341
http://dx.doi.org/10.1039/c5sc02269j

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