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The ligand unwrapping/rewrapping pathway that exchanges metals in S-acetylated, hexacoordinate N(2)S(2)O(2) complexes
The effect of S-acetylation in MN(2)S(2) complexes on metal exchange reactivity was examined in a series of MN(2)S(2)O(2) complexes. While clean exchange processes do not occur for the MN(2)S(2) derivatives where formation of S-bridged aggregates predominate, acetylation permits the metal exchange w...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5954489/ https://www.ncbi.nlm.nih.gov/pubmed/29896341 http://dx.doi.org/10.1039/c5sc02269j |