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Catalytic insertion of E–H bonds (E = C, N, P, S) into heterocumulenes by amido–actinide complexes

We report herein the actinide-mediated insertion of E–H bonds (E = C, N, P, S) into various heterocumulenes including carbodiimides, isocyanates, and isothiocyanates. The precatalysts are prepared by a simple, one-pot procedure using readily available starting materials, and challenging insertions a...

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Detalles Bibliográficos
Autores principales: Batrice, Rami J., Eisen, Moris S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5954617/
https://www.ncbi.nlm.nih.gov/pubmed/29896364
http://dx.doi.org/10.1039/c5sc02746b