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Catalytic insertion of E–H bonds (E = C, N, P, S) into heterocumulenes by amido–actinide complexes
We report herein the actinide-mediated insertion of E–H bonds (E = C, N, P, S) into various heterocumulenes including carbodiimides, isocyanates, and isothiocyanates. The precatalysts are prepared by a simple, one-pot procedure using readily available starting materials, and challenging insertions a...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5954617/ https://www.ncbi.nlm.nih.gov/pubmed/29896364 http://dx.doi.org/10.1039/c5sc02746b |