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A structural view of synthetic cofactor integration into [FeFe]-hydrogenases
[FeFe]-hydrogenases are nature's fastest catalysts for the evolution or oxidation of hydrogen. Numerous synthetic model complexes for the [2Fe] subcluster (2Fe(H)) of their active site are known, but so far none of these could compete with the enzymes. The complex Fe(2)[μ-(SCH(2))(2)X](CN)(2)(C...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5954619/ https://www.ncbi.nlm.nih.gov/pubmed/29896366 http://dx.doi.org/10.1039/c5sc03397g |