Acidity and basicity interplay in amide and imide self-association

Amides dimerise more strongly than imides despite their lower acidity. Such an unexpected result has been rationalised in terms of the Jorgensen Secondary Interactions Hypothesis (JSIH) that involves the spectator (C[double bond, length as m-dash]O(S)) and H-bonded (C[double bond, length as m-dash]O...

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Detalles Bibliográficos
Autores principales: Vallejo Narváez, Wilmer E., Jiménez, Eddy I., Romero-Montalvo, Eduardo, Sauza-de la Vega, Arturo, Quiroz-García, Beatriz, Hernández-Rodríguez, Marcos, Rocha-Rinza, Tomás
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956980/
https://www.ncbi.nlm.nih.gov/pubmed/29896381
http://dx.doi.org/10.1039/c8sc01020j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956980/
https://www.ncbi.nlm.nih.gov/pubmed/29896381
http://dx.doi.org/10.1039/c8sc01020j

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