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Acidity and basicity interplay in amide and imide self-association
Amides dimerise more strongly than imides despite their lower acidity. Such an unexpected result has been rationalised in terms of the Jorgensen Secondary Interactions Hypothesis (JSIH) that involves the spectator (C[double bond, length as m-dash]O(S)) and H-bonded (C[double bond, length as m-dash]O...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956980/ https://www.ncbi.nlm.nih.gov/pubmed/29896381 http://dx.doi.org/10.1039/c8sc01020j |