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Why one can expect large rectification in molecular junctions based on alkane monothiols and why rectification is so modest

Many attempts to obtain high current rectification ratios (RRs) in molecular electronics are triggered by a potentiometer rule argument, which predicts that a strongly asymmetric location of the dominant molecular orbital yields large RR-values. Invoking this argument, molecular junctions based on a...

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Detalles Bibliográficos
Autores principales: Xie, Zuoti, Bâldea, Ioan, Frisbie, C. Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956982/
https://www.ncbi.nlm.nih.gov/pubmed/29896387
http://dx.doi.org/10.1039/c8sc00938d