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Iodine-catalyzed diazo activation to access radical reactivity

Transition-metal-catalyzed diazo activation is a classical way to generate metal carbene, which are valuable intermediates in synthetic organic chemistry. An alternative iodine-catalyzed diazo activation is disclosed herein under either photo-initiated or thermal-initiated conditions, which represen...

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Detalles Bibliográficos
Autores principales: Li, Pan, Zhao, Jingjing, Shi, Lijun, Wang, Jin, Shi, Xiaodong, Li, Fuwei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5958049/
https://www.ncbi.nlm.nih.gov/pubmed/29773787
http://dx.doi.org/10.1038/s41467-018-04331-4