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Stereodivergent synthesis of vicinal quaternary-quaternary stereocenters and bioactive hyperolactones

Although great success has been achieved in asymmetric Claisen rearrangement for the synthesis of chiral γ,δ-unsaturated carbonyl compounds bearing vicinal tertiary-quaternary stereocenters, the development of asymmetric versions for stereodivergent construction of adjacent quaternary-quaternary ste...

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Detalles Bibliográficos
Autores principales: Zheng, Haifeng, Wang, Yan, Xu, Chaoran, Xu, Xi, Lin, Lili, Liu, Xiaohua, Feng, Xiaoming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5958103/
https://www.ncbi.nlm.nih.gov/pubmed/29773786
http://dx.doi.org/10.1038/s41467-018-04123-w