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β C–H di-halogenation via iterative hydrogen atom transfer
A radical relay strategy for mono- and di-halogenation (iodination, bromination, and chlorination) of sp(3) C–H bonds has been developed. This first example of β C–H di-halogenation is achieved through sequential C–H abstraction by iterative, hydrogen atom transfer (HAT). A double C–H functionalizat...
Autores principales: | Wappes, Ethan A., Vanitcha, Avassaya, Nagib, David A. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5958344/ https://www.ncbi.nlm.nih.gov/pubmed/29896392 http://dx.doi.org/10.1039/c8sc01214h |
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