Chemo- and regioselective oxygenation of C(sp(3))–H bonds in aliphatic alcohols using a covalently bound directing activator and atmospheric oxygen

Chemically reactive directing groups (directing activators) represent a promising strategy for mild and regioselective C(sp(3))–H functionalization. The use of a radical N-oxyl directing activator promoted the aerobic oxygenation of benzylic, propargylic, tertiary, and unactivated acyclic methylene...

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Detalles Bibliográficos
Autores principales: Ozawa, Jun, Tashiro, Masayuki, Ni, Jizhi, Oisaki, Kounosuke, Kanai, Motomu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5965247/
https://www.ncbi.nlm.nih.gov/pubmed/29899913
http://dx.doi.org/10.1039/c5sc04476f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5965247/
https://www.ncbi.nlm.nih.gov/pubmed/29899913
http://dx.doi.org/10.1039/c5sc04476f

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