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Chemo- and regioselective oxygenation of C(sp(3))–H bonds in aliphatic alcohols using a covalently bound directing activator and atmospheric oxygen
Chemically reactive directing groups (directing activators) represent a promising strategy for mild and regioselective C(sp(3))–H functionalization. The use of a radical N-oxyl directing activator promoted the aerobic oxygenation of benzylic, propargylic, tertiary, and unactivated acyclic methylene...
Autores principales: | Ozawa, Jun, Tashiro, Masayuki, Ni, Jizhi, Oisaki, Kounosuke, Kanai, Motomu |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5965247/ https://www.ncbi.nlm.nih.gov/pubmed/29899913 http://dx.doi.org/10.1039/c5sc04476f |
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