Successive C–C bond cleavage, fluorination, trifluoromethylthio- and pentafluorophenylthiolation under metal-free conditions to provide compounds with dual fluoro-functionalization

The selective C–C bond cleavage and simultaneous formation of two C–F bonds and one C–S bond in β-keto esters with nucleophilic fluorination reagents such as DAST under metal-free/catalyst-free conditions is disclosed. Double fluorination at two remote carbons with additional dialkylamino-sulfenylat...

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Detalles Bibliográficos
Autores principales: Saidalimu, Ibrayim, Suzuki, Shugo, Tokunaga, Etsuko, Shibata, Norio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5968529/
https://www.ncbi.nlm.nih.gov/pubmed/29899937
http://dx.doi.org/10.1039/c5sc04208a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5968529/
https://www.ncbi.nlm.nih.gov/pubmed/29899937
http://dx.doi.org/10.1039/c5sc04208a

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