Experimental and Theoretical Identification of the Origin of Magnetic Anisotropy in Intermediate Spin Iron(III) Complexes

The complexes [FeL(N2S2)X] [in which L(N2S2)=2,2′‐(2,2′‐bipryridine‐6,6′‐diyl)bis(1,1′‐diphenylethanethiolate) and X=Cl, Br and I], characterized crystallographically earlier and here (Fe(L)Br), reveal a square pyramidal coordinated Fe(III) ion. Unusually, all three complexes have intermediate spin...

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Detalles Bibliográficos
Autores principales: Wang, Lianke, Zlatar, Matija, Vlahović, Filip, Demeshko, Serhiy, Philouze, Christian, Molton, Florian, Gennari, Marcello, Meyer, Franc, Duboc, Carole, Gruden, Maja
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5969241/
https://www.ncbi.nlm.nih.gov/pubmed/29447424
http://dx.doi.org/10.1002/chem.201705989

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5969241/
https://www.ncbi.nlm.nih.gov/pubmed/29447424
http://dx.doi.org/10.1002/chem.201705989

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