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Ring‐Expanded N‐Heterocyclic Carbenes for Copper‐Mediated Azide–Alkyne Click Cycloaddition Reactions

A series of well‐defined copper(I) complexes bearing ring‐expanded N‐heterocyclic carbene (NHC) ligands has been applied to the azide–alkyne cycloaddition reaction. The obtained results notably showed that the six‐membered NHC ligands outperform well‐established five‐membered ones. [CuI(Mes‐6)] disp...

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Detalles Bibliográficos
Autores principales: Sebest, Filip, Dunsford, Jay J., Adams, Matthew, Pivot, Jeremy, Newman, Paul D., Díez‐González, Silvia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5969269/
https://www.ncbi.nlm.nih.gov/pubmed/29861792
http://dx.doi.org/10.1002/cctc.201701992