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Hydrogen gas generation using a metal-free fluorinated porphyrin
Free-base meso-tetra(pentafluorophenyl)porphyrin, 1, is electrocatalytically active for hydrogen gas generation in the presence of p-toluenesulfonic acid. The electrochemical potential of hydrogen evolution (–1.31 V vs. Fc/Fc(+) in THF) is comparable to those of metal containing electrocatalysts suc...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5969493/ https://www.ncbi.nlm.nih.gov/pubmed/29899963 http://dx.doi.org/10.1039/c8sc00093j |