Identification of a biliverdin geometric isomer by means of HPLC/ESI–MS and NMR spectroscopy. Differentiation of the isomers by using fragmentation “in-source”

ABSTRACT: A commercially available biliverdin sample was analyzed by means of HPLC/ESI–MS and NMR spectroscopy. It was been found that beside the main IXα 5Z,10Z,15Z isomer, the sample contains also the geometric isomer IXα 5Z,10Z,15E. It was also found the isomers behave differentially upon “in-sou...

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Detalles Bibliográficos
Autores principales: Frański, Rafał, Gierczyk, Błażej, Popenda, Łukasz, Kasperkowiak, Małgorzata, Pędzinski, Tomasz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Vienna 2018
Materias:
Original Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5972171/
https://www.ncbi.nlm.nih.gov/pubmed/29887645
http://dx.doi.org/10.1007/s00706-018-2161-7

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5972171/
https://www.ncbi.nlm.nih.gov/pubmed/29887645
http://dx.doi.org/10.1007/s00706-018-2161-7

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