Photochemical reductive homologation of hydrogen cyanide using sulfite and ferrocyanide

Photoredox cycling during UV irradiation of ferrocyanide ([Fe(II)(CN)(6)](4–)) in the presence of stoichiometric sulfite (SO(3)(2–)) is shown to be an extremely effective way to drive the reductive homologation of hydrogen cyanide (HCN) to simple sugars and precursors of hydroxy acids and amino acid...

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Detalles Bibliográficos
Autores principales: Xu, Jianfeng, Ritson, Dougal J., Ranjan, Sukrit, Todd, Zoe R., Sasselov, Dimitar D., Sutherland, John D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5972737/
https://www.ncbi.nlm.nih.gov/pubmed/29761807
http://dx.doi.org/10.1039/c8cc01499j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5972737/
https://www.ncbi.nlm.nih.gov/pubmed/29761807
http://dx.doi.org/10.1039/c8cc01499j

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