Photochemical reductive homologation of hydrogen cyanide using sulfite and ferrocyanide

Photoredox cycling during UV irradiation of ferrocyanide ([Fe(II)(CN)(6)](4–)) in the presence of stoichiometric sulfite (SO(3)(2–)) is shown to be an extremely effective way to drive the reductive homologation of hydrogen cyanide (HCN) to simple sugars and precursors of hydroxy acids and amino acid...

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Detalles Bibliográficos
Autores principales: Xu, Jianfeng, Ritson, Dougal J., Ranjan, Sukrit, Todd, Zoe R., Sasselov, Dimitar D., Sutherland, John D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5972737/
https://www.ncbi.nlm.nih.gov/pubmed/29761807
http://dx.doi.org/10.1039/c8cc01499j
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author Xu, Jianfeng
Ritson, Dougal J.
Ranjan, Sukrit
Todd, Zoe R.
Sasselov, Dimitar D.
Sutherland, John D.
author_facet Xu, Jianfeng
Ritson, Dougal J.
Ranjan, Sukrit
Todd, Zoe R.
Sasselov, Dimitar D.
Sutherland, John D.
author_sort Xu, Jianfeng
collection PubMed
description Photoredox cycling during UV irradiation of ferrocyanide ([Fe(II)(CN)(6)](4–)) in the presence of stoichiometric sulfite (SO(3)(2–)) is shown to be an extremely effective way to drive the reductive homologation of hydrogen cyanide (HCN) to simple sugars and precursors of hydroxy acids and amino acids.
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spelling pubmed-59727372018-06-13 Photochemical reductive homologation of hydrogen cyanide using sulfite and ferrocyanide Xu, Jianfeng Ritson, Dougal J. Ranjan, Sukrit Todd, Zoe R. Sasselov, Dimitar D. Sutherland, John D. Chem Commun (Camb) Chemistry Photoredox cycling during UV irradiation of ferrocyanide ([Fe(II)(CN)(6)](4–)) in the presence of stoichiometric sulfite (SO(3)(2–)) is shown to be an extremely effective way to drive the reductive homologation of hydrogen cyanide (HCN) to simple sugars and precursors of hydroxy acids and amino acids. Royal Society of Chemistry 2018-06-04 2018-05-15 /pmc/articles/PMC5972737/ /pubmed/29761807 http://dx.doi.org/10.1039/c8cc01499j Text en This journal is © The Royal Society of Chemistry 2018 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Xu, Jianfeng
Ritson, Dougal J.
Ranjan, Sukrit
Todd, Zoe R.
Sasselov, Dimitar D.
Sutherland, John D.
Photochemical reductive homologation of hydrogen cyanide using sulfite and ferrocyanide
title Photochemical reductive homologation of hydrogen cyanide using sulfite and ferrocyanide
title_full Photochemical reductive homologation of hydrogen cyanide using sulfite and ferrocyanide
title_fullStr Photochemical reductive homologation of hydrogen cyanide using sulfite and ferrocyanide
title_full_unstemmed Photochemical reductive homologation of hydrogen cyanide using sulfite and ferrocyanide
title_short Photochemical reductive homologation of hydrogen cyanide using sulfite and ferrocyanide
title_sort photochemical reductive homologation of hydrogen cyanide using sulfite and ferrocyanide
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5972737/
https://www.ncbi.nlm.nih.gov/pubmed/29761807
http://dx.doi.org/10.1039/c8cc01499j
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AT toddzoer photochemicalreductivehomologationofhydrogencyanideusingsulfiteandferrocyanide
AT sasselovdimitard photochemicalreductivehomologationofhydrogencyanideusingsulfiteandferrocyanide
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