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Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings

Despite the fact that non-aqueous uranium chemistry is over 60 years old, most polarised-covalent uranium-element multiple bonds involve formal uranium oxidation states IV, V, and VI. The paucity of uranium(III) congeners is because, in common with metal-ligand multiple bonding generally, such linka...

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Detalles Bibliográficos
Autores principales: Wooles, Ashley J., Mills, David P., Tuna, Floriana, McInnes, Eric J. L., Law, Gareth T. W., Fuller, Adam J., Kremer, Felipe, Ridgway, Mark, Lewis, William, Gagliardi, Laura, Vlaisavljevich, Bess, Liddle, Stephen T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5974406/
https://www.ncbi.nlm.nih.gov/pubmed/29844376
http://dx.doi.org/10.1038/s41467-018-04560-7