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Enantioselective synthesis of α-alkenyl α-amino acids via N–H insertion reactions

A new highly enantioselective route to α-alkenyl α-amino acid derivatives, which are important naturally occurring compounds with attractive bioactivity and synthetic utility, was developed using a N–H insertion reaction of vinyldiazoacetates and tert-butyl carbamate cooperatively catalyzed by achir...

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Detalles Bibliográficos
Autores principales: Guo, Jun-Xia, Zhou, Ting, Xu, Bin, Zhu, Shou-Fei, Zhou, Qi-Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5975786/
https://www.ncbi.nlm.nih.gov/pubmed/29910866
http://dx.doi.org/10.1039/c5sc03558a