How π back-donation quantitatively controls the CO stretching response in classical and non-classical metal carbonyl complexes

The CO stretching response upon coordination to a metal M to form [(L)(n)M(CO)](m) complexes (L is an auxiliary ligand) is investigated in relation to the σ donation and π back-donation components of the M–CO bond and to the electrostatic effect exerted by the ligand–metal fragment. Our analysis enc...

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Detalles Bibliográficos
Autores principales: Bistoni, Giovanni, Rampino, Sergio, Scafuri, Nicola, Ciancaleoni, Gianluca, Zuccaccia, Daniele, Belpassi, Leonardo, Tarantelli, Francesco
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5975789/
https://www.ncbi.nlm.nih.gov/pubmed/29910872
http://dx.doi.org/10.1039/c5sc02971f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5975789/
https://www.ncbi.nlm.nih.gov/pubmed/29910872
http://dx.doi.org/10.1039/c5sc02971f

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