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Rational synthesis of normal, abnormal and anionic NHC–gallium alkyl complexes: structural, stability and isomerization insights

Advancing the rational design of main-group N-heterocyclic carbene complexes, this study reports the synthesis, X-ray crystallographic and NMR spectroscopic characterisation of a novel series of Ga complexes containing neutral or anionic NHC ligands using the unsaturated carbene IPr (IPr = 1,3-bis-(...

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Detalles Bibliográficos
Autores principales: Uzelac, Marina, Hernán-Gómez, Alberto, Armstrong, David R., Kennedy, Alan R., Hevia, Eva
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5975842/
https://www.ncbi.nlm.nih.gov/pubmed/29910864
http://dx.doi.org/10.1039/c5sc02086g