Spin Crossover in a Hexaamineiron(II) Complex: Experimental Confirmation of a Computational Prediction

Single crystal structural analysis of [Fe(II)(tame)(2)]Cl(2)⋅MeOH (tame=1,1,1‐tris(aminomethyl)ethane) as a function of temperature reveals a smooth crossover between a high temperature high‐spin octahedral d (6) state and a low temperature low‐spin ground state without change of the symmetry of the...

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Detalles Bibliográficos
Autores principales: Bernhardt, Paul V., Bilyj, Jessica K., Brosius, Victor, Chernyshov, Dmitry, Deeth, Robert J., Foscato, Marco, Jensen, Vidar R., Mertes, Nicole, Riley, Mark J., Törnroos, Karl W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5988046/
https://www.ncbi.nlm.nih.gov/pubmed/29315883
http://dx.doi.org/10.1002/chem.201705439

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5988046/
https://www.ncbi.nlm.nih.gov/pubmed/29315883
http://dx.doi.org/10.1002/chem.201705439

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