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Kekulé diradicaloids derived from a classical N-heterocyclic carbene

The direct double carbenylation of 1,4-diiodobenzene and 4,4′-dibromobiphenyl with a classical N-heterocyclic carbene, SIPr (1) (SIPr = :C{N(2,6-iPr(2)C(6)H(3))}(2)CH(2)CH(2)), by means of nickel catalysis gives rise to 1,3-imidazolinium salts [(SIPr)(C(6)H(4))(SIPr)](I)(2) (2) and [(SIPr)(C(6)H(4))...

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Detalles Bibliográficos
Autores principales: Rottschäfer, Dennis, Neumann, Beate, Stammler, Hans-Georg, Andrada, Diego M., Ghadwal, Rajendra S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5989652/
https://www.ncbi.nlm.nih.gov/pubmed/29938024
http://dx.doi.org/10.1039/c8sc01209a