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Kekulé diradicaloids derived from a classical N-heterocyclic carbene
The direct double carbenylation of 1,4-diiodobenzene and 4,4′-dibromobiphenyl with a classical N-heterocyclic carbene, SIPr (1) (SIPr = :C{N(2,6-iPr(2)C(6)H(3))}(2)CH(2)CH(2)), by means of nickel catalysis gives rise to 1,3-imidazolinium salts [(SIPr)(C(6)H(4))(SIPr)](I)(2) (2) and [(SIPr)(C(6)H(4))...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5989652/ https://www.ncbi.nlm.nih.gov/pubmed/29938024 http://dx.doi.org/10.1039/c8sc01209a |