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Improvement of the selectivity of isophorone hydrogenation by Lewis acids

The selective hydrogenation of isophorone (3,5,5-trimethyl-2- cyclohexen-1-one) to produce 3,3,5-trimethylcyclohexanone (TMCH), an important organic solvent and pharmaceutical intermediate, is of significance in industry. However, the over-hydrogenation to produce the by-product 3,3,5-trimethylcyclo...

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Detalles Bibliográficos
Autores principales: Hou, Yucui, Ren, Shuhang, Niu, Muge, Wu, Weize
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society Publishing 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5990831/
https://www.ncbi.nlm.nih.gov/pubmed/29892356
http://dx.doi.org/10.1098/rsos.171523