Formation of a new type of uranium(iv) poly-oxo cluster {U(38)} based on a controlled release of water via esterification reaction

A new strategy for the synthesis of large poly-oxo clusters bearing 38 tetravalent uranium atoms {U(38)} has been developed by controlling the water release from the esterification reaction between a carboxylic acid and an alcohol. The molecular entity [U(38)O(56)Cl(40)(H(2)O)(2)(ipa)(20)]·(ipa)(x)...

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Detalles Bibliográficos
Autores principales: Martin, Nicolas P., Volkringer, Christophe, Henry, Natacha, Trivelli, Xavier, Stoclet, Grégory, Ikeda-Ohno, Atsushi, Loiseau, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994743/
https://www.ncbi.nlm.nih.gov/pubmed/29938031
http://dx.doi.org/10.1039/c8sc00752g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994743/
https://www.ncbi.nlm.nih.gov/pubmed/29938031
http://dx.doi.org/10.1039/c8sc00752g

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