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Formation of a new type of uranium(iv) poly-oxo cluster {U(38)} based on a controlled release of water via esterification reaction
A new strategy for the synthesis of large poly-oxo clusters bearing 38 tetravalent uranium atoms {U(38)} has been developed by controlling the water release from the esterification reaction between a carboxylic acid and an alcohol. The molecular entity [U(38)O(56)Cl(40)(H(2)O)(2)(ipa)(20)]·(ipa)(x)...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994743/ https://www.ncbi.nlm.nih.gov/pubmed/29938031 http://dx.doi.org/10.1039/c8sc00752g |