Thermodynamic and reactivity studies of a tin corrole–cobalt porphyrin heterobimetallic complex

A heterobimetallic complex, (TPFC)Sn–Co(TAP) (TPFC = 5,10,15-tris(pentafluorophenyl)corrole, TAP = 5,10,15,20-tetrakis(p-methoxyphenyl)porphyrin), was synthesized. The complex featured a Sn–Co bond with a bond dissociation enthalpy (BDE) of 30.2 ± 0.9 kcal mol(–1) and a bond dissociation Gibbs free...

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Detalles Bibliográficos
Autores principales: Wang, Zikuan, Yao, Zhengmin, Lyu, Zeyu, Xiong, Qinsi, Wang, Bingwu, Fu, Xuefeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994744/
https://www.ncbi.nlm.nih.gov/pubmed/29938028
http://dx.doi.org/10.1039/c8sc01269e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994744/
https://www.ncbi.nlm.nih.gov/pubmed/29938028
http://dx.doi.org/10.1039/c8sc01269e

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