Cargando…
Thermodynamic and reactivity studies of a tin corrole–cobalt porphyrin heterobimetallic complex
A heterobimetallic complex, (TPFC)Sn–Co(TAP) (TPFC = 5,10,15-tris(pentafluorophenyl)corrole, TAP = 5,10,15,20-tetrakis(p-methoxyphenyl)porphyrin), was synthesized. The complex featured a Sn–Co bond with a bond dissociation enthalpy (BDE) of 30.2 ± 0.9 kcal mol(–1) and a bond dissociation Gibbs free...
| Autores principales: | , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994744/ https://www.ncbi.nlm.nih.gov/pubmed/29938028 http://dx.doi.org/10.1039/c8sc01269e |