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Trimerisation of carbon suboxide at a di-titanium centre to form a pyrone ring system

The reaction of the syn-bimetallic bis(pentalene)dititanium complex Ti(2)(μ:η(5),η(5)-Pn(†))(2) (Pn(†) = C(8)H(4)(1,4-Si(i)Pr(3))(2)) 1 with carbon suboxide (O[double bond, length as m-dash]C[double bond, length as m-dash]C[double bond, length as m-dash]C[double bond, length as m-dash]O, C(3)O(2)) r...

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Detalles Bibliográficos
Autores principales: Tsoureas, Nikolaos, Green, Jennifer C., Cloke, F. Geoffrey N., Puschmann, Horst, Roe, S. Mark, Tizzard, Graham
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994745/
https://www.ncbi.nlm.nih.gov/pubmed/29938029
http://dx.doi.org/10.1039/c8sc01127c