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Trimerisation of carbon suboxide at a di-titanium centre to form a pyrone ring system
The reaction of the syn-bimetallic bis(pentalene)dititanium complex Ti(2)(μ:η(5),η(5)-Pn(†))(2) (Pn(†) = C(8)H(4)(1,4-Si(i)Pr(3))(2)) 1 with carbon suboxide (O[double bond, length as m-dash]C[double bond, length as m-dash]C[double bond, length as m-dash]C[double bond, length as m-dash]O, C(3)O(2)) r...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994745/ https://www.ncbi.nlm.nih.gov/pubmed/29938029 http://dx.doi.org/10.1039/c8sc01127c |