A supramolecular radical cation: folding-enhanced electrostatic effect for promoting radical-mediated oxidation

We report a supramolecular strategy to promote radical-mediated Fenton oxidation by the rational design of a folded host–guest complex based on cucurbit[8]uril (CB[8]). In the supramolecular complex between CB[8] and a derivative of 1,4-diketopyrrolo[3,4-c]pyrrole (DPP), the carbonyl groups of CB[8]...

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Detalles Bibliográficos
Autores principales: Tang, Bohan, Li, Wan-Lu, Jiao, Yang, Lu, Jun-Bo, Xu, Jiang-Fei, Wang, Zhiqiang, Li, Jun, Zhang, Xi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994746/
https://www.ncbi.nlm.nih.gov/pubmed/29938030
http://dx.doi.org/10.1039/c8sc01434e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994746/
https://www.ncbi.nlm.nih.gov/pubmed/29938030
http://dx.doi.org/10.1039/c8sc01434e

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