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A supramolecular radical cation: folding-enhanced electrostatic effect for promoting radical-mediated oxidation
We report a supramolecular strategy to promote radical-mediated Fenton oxidation by the rational design of a folded host–guest complex based on cucurbit[8]uril (CB[8]). In the supramolecular complex between CB[8] and a derivative of 1,4-diketopyrrolo[3,4-c]pyrrole (DPP), the carbonyl groups of CB[8]...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994746/ https://www.ncbi.nlm.nih.gov/pubmed/29938030 http://dx.doi.org/10.1039/c8sc01434e |