Metal-free borylative dearomatization of indoles: exploring the divergent reactivity of aminoborane C–H borylation catalysts

While the dearomatization of indoles by carbon–boron bond forming reactions is new and quite promising, they are so far mainly metal-catalyzed. Here, we establish the use of metal-free catalysts in promoting such reactions in an atom-efficient way. The in situ generated ambiphilic aminoborane cataly...

Descripción completa

Detalles Bibliográficos
Autores principales: Jayaraman, Arumugam, Misal Castro, Luis C., Desrosiers, Vincent, Fontaine, Frédéric-Georges
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994747/
https://www.ncbi.nlm.nih.gov/pubmed/29938036
http://dx.doi.org/10.1039/c8sc01093e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994747/
https://www.ncbi.nlm.nih.gov/pubmed/29938036
http://dx.doi.org/10.1039/c8sc01093e

Ejemplares similares