A DFT-based mechanistic proposal for the light-driven insertion of dioxygen into Pt(ii)–C bonds

The photocatalyzed insertion of dioxygen into the Pt(ii)–methyl bond in terpyridine platinum complexes has been shown to proceed efficiently, but its mechanism remains a challenge. In particular, there are serious counter-intuitive differences in the reactivity of structurally similar complexes. M06...

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Detalles Bibliográficos
Autores principales: Fernández-Alvarez, Victor M., Ho, Sarah K. Y., Britovsek, George J. P., Maseras, Feliu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994795/
https://www.ncbi.nlm.nih.gov/pubmed/29938033
http://dx.doi.org/10.1039/c8sc01161c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994795/
https://www.ncbi.nlm.nih.gov/pubmed/29938033
http://dx.doi.org/10.1039/c8sc01161c

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