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A DFT-based mechanistic proposal for the light-driven insertion of dioxygen into Pt(ii)–C bonds
The photocatalyzed insertion of dioxygen into the Pt(ii)–methyl bond in terpyridine platinum complexes has been shown to proceed efficiently, but its mechanism remains a challenge. In particular, there are serious counter-intuitive differences in the reactivity of structurally similar complexes. M06...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994795/ https://www.ncbi.nlm.nih.gov/pubmed/29938033 http://dx.doi.org/10.1039/c8sc01161c |