Enantioselective radical process for synthesis of chiral indolines by metalloradical alkylation of diverse C(sp(3))–H bonds

A new C–C bond formation strategy based on enantioselective radical alkylation of C(sp(3))–H bonds via Co(ii)-based metalloradical catalysis has been demonstrated for stereoselective synthesis of chiral indolines. The Co(ii)-based system enables activation of aryldiazomethanes as radical precursors...

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Detalles Bibliográficos
Autores principales: Wen, Xin, Wang, Yong, Zhang, X. Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994879/
https://www.ncbi.nlm.nih.gov/pubmed/29938039
http://dx.doi.org/10.1039/c8sc01476k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994879/
https://www.ncbi.nlm.nih.gov/pubmed/29938039
http://dx.doi.org/10.1039/c8sc01476k

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