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The robust, readily available cobalt(iii) trication [Co(NH(2)CHPhCHPhNH(2))(3)](3+) is a progenitor of broadly applicable chirality and prochirality sensing agents
When NMR spectra of chiral racemic organic molecules containing a Lewis basic functional group are recorded in the presence of air and water stable salts of the cobalt(iii) trication [Co((S,S)-NH(2)CHPhCHPhNH(2))(3)](3+) (2(3+)), separate signals are usually observed for the enantiomers (28 diverse...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994889/ https://www.ncbi.nlm.nih.gov/pubmed/29938040 http://dx.doi.org/10.1039/c8sc01510d |