Facile synthesis of α-aminoboronic acids from amines and potassium acyltrifluoroborates (KATs) via trifluoroborate-iminiums (TIMs)

We report the facile formation of trifluoroborate-iminiums (TIMs) from potassium acyltrifluoroborates (KATs) and the transformation of TIMs to α-aminotrifluoroborates by reduction or Grignard additions. Conditions for the hydrolysis of α-aminotrifluoroborates to α-aminoboronic acids, which are impor...

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Detalles Bibliográficos
Autores principales: Shiro, Tomoya, Schuhmacher, Anne, Jackl, Moritz K., Bode, Jeffrey W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6000978/
https://www.ncbi.nlm.nih.gov/pubmed/29997873
http://dx.doi.org/10.1039/c8sc01486h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6000978/
https://www.ncbi.nlm.nih.gov/pubmed/29997873
http://dx.doi.org/10.1039/c8sc01486h

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