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Dehydrogenative coupling of 4-substituted pyridines mediated by a zirconium(ii) synthon: reaction pathways and dead ends
The mechanism of the reductive homocoupling of pyridine derivatives mediated by the Zr(II) synthon [(PNP)Zr(η(6)-toluene)Cl] (1) has been investigated. Selective transformation into three different types of product complexes has been observed, depending on the N-heterocyclic substrate employed: the...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6001252/ https://www.ncbi.nlm.nih.gov/pubmed/29997877 http://dx.doi.org/10.1039/c8sc01025k |